Allylthioketone Mediated Free Radical Polymerization of Methacrylates
نویسندگان
چکیده
منابع مشابه
The Mechanism of Stereoregulation in Free-Radical Polymerization of Bulky Methacrylates
Theoretical calculations are performed to explore the origin of inherent tacticity in bulky methacrylates. Geometries and conformer distributions of monomers and oligomeric propagating radicals are calculated to study the impact of steric bulk and π-stacking interactions on the preferences for meso versus isotactic propagation. Consistent with the previous qualitative analyses by Satoh and Kami...
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ژورنال
عنوان ژورنال: Polymers
سال: 2017
ISSN: 2073-4360
DOI: 10.3390/polym9110608